I'm confused by your question, but I may be able to answer. I was never a Tank Soldier, but I am Field Artillery and the principles and operation of a tank gun are the same.
IF (and that's a mighty big IF) a round was shot straight down the barrel of a tank and was able to hit the very end of the tank round, it would disable the fuse which would render the round a dud. It would fire and go out of the tube and probably hit what it was aimed at, but no "boom" without the fuze. The fuze is not armed until it leaves the tube and rotates a set amount of rotations, so it would not set off the round inside the chamber.
It's more likely that the round you fired (if you could get it in the muzzle brake) would travel downt he length of the tube and strike the tank round, damaging it. It's aerodynamics might be affected but it would probably still be able to be fired.
IF you were lucky enough to fire down the barrel of the tank with no round in the chamber and before the breech was closed, the round you fired would of course, bounce around INSIDE the turret causing all sorts of havoc, but that's a VERY short window of time.
Does that answer your question?